The Gamma Irradiation of Aqueous Solutions of Urea. Implications for Chemical Evolution

Authors: R. Navarro-González, A. Negrón-Mendoza, E. Chacón 0.05moledm-3,Oz-free aqueous solutions of urea were studies after receiving various doses of 6°Co gamma rays(0.14-600kGy). Urea was found to be relatively stable under radiation; its radiation chemical yield of decomposition was 0.47. Hydrogen (G=0.50), carbon dioxide (G=0.44), ammonia (G=0.22), oxalic acid (G=0.0054), malonic acid (G=0.000064)and three unidentified oligomers were found to be the…

The Radiolysis of Aqueous Acetonitrile: Compounds of Interest to Chemical Evolution Studies

Authors: I.G. Draganić, S. Jovanić, V. Niketić, Z.D. Draganić, Oxygen-free aqueous solutions of CH3CN (0.1 M, pH 6) were ex- posed to gamma rays from a 60Co source,the mixture of non volatile radiolytic products was fractionated and the fractions were analysed. Succinic,maleic, fumaric, malonic andpyruvic acids were identified. Glycol aldehyde,glucose and probably ribose were observed in the hydrolysate of fractionated…